Literature DB >> 28598561

Zinc-Zinc Double Bonds: A Theoretical Study.

Jorge Echeverría1, Andrés Falceto1, Santiago Alvarez1.   

Abstract

While double bonds are known for transition metals of Groups 9 and 10 as well as for boron and p-block elements of Groups 14-16, Zn sits in a small region of the periodic table with no well-characterized double bonds. A qualitative reasoning indicates that zero-valent zinc has the potential to form Zn=Zn double bonds. A computational study in search for complexes that might showcase this new bond type is presented here.
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  density functional calculations; double bonds; metal-metal bonding; zinc

Year:  2017        PMID： 28598561     DOI： 10.1002/anie.201702171

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  2 in total

1.  Atomic-scale combination of germanium-zinc nanofibers for structural and electrochemical evolution.

Authors:  Gyujin Song; Jun Young Cheong; Chanhoon Kim; Langli Luo; Chihyun Hwang; Sungho Choi; Jaegeon Ryu; Sungho Kim; Woo-Jin Song; Hyun-Kon Song; Chongmin Wang; Il-Doo Kim; Soojin Park
Journal:  Nat Commun       Date:  2019-05-30       Impact factor: 14.919

2.  Asymmetric Solvation of the Zinc Dimer Cation Revealed by Infrared Multiple Photon Dissociation Spectroscopy of Zn2+(H2O)n (n = 1-20).

Authors:  Ethan M Cunningham; Thomas Taxer; Jakob Heller; Milan Ončák; Christian van der Linde; Martin K Beyer
Journal:  Int J Mol Sci       Date:  2021-06-02       Impact factor: 5.923
  2 in total

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