| Literature DB >> 28590758 |
Manjur O Akram1,2, Pramod S Mali1, Nitin T Patil1,2.
Abstract
A method for the cross-coupling reactions of aryldiazonium salts with trialkylallylsilanes via merged gold/photoredox catalysis is described. The reaction is proposed to proceed through a photoredox-promoted generation of an electrophilic arylgold(III) intermediate that undergoes transmetalation with allyltrimethylsilane to form allylarenes.Entities:
Year: 2017 PMID: 28590758 DOI: 10.1021/acs.orglett.7b01148
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005