| Literature DB >> 28584386 |
A Koutian1, M J Assael1, M L Huber2, R A Perkins2.
Abstract
New, wide-range reference equations for the thermal conductivity of cyclohexane as a function of temperature and density are presented. The equations are based in part upon a body of experimental data that has been critically assessed for internal consistency and for agreement with theory whenever possible. We estimate the uncertainty (at the 95% confidence level) for the thermal conductivity of cyclohexane from the triple point (279.86 K) to 650 K at pressures up to 175 MPa to be 4% for the compressed liquid and supercritical phases. For the low-pressure gas phase (up to 0.1 MPa) over the temperature range 280 K to 680 K, the estimated uncertainty is 2.5%. Uncertainties in the critical region are much larger, since the thermal conductivity approaches infinity at the critical point and is very sensitive to small changes in density.Entities:
Keywords: critical phenomena; cyclohexane; reference correlations; thermal conductivity; transport properties
Year: 2017 PMID: 28584386 PMCID: PMC5455799 DOI: 10.1063/1.4974325
Source DB: PubMed Journal: J Phys Chem Ref Data ISSN: 0047-2689 Impact factor: 2.828