Literature DB >> 28584386

Reference Correlation of the Thermal Conductivity of Cyclohexane from the Triple Point to 640 K and up to 175 MPa.

A Koutian1, M J Assael1, M L Huber2, R A Perkins2.   

Abstract

New, wide-range reference equations for the thermal conductivity of cyclohexane as a function of temperature and density are presented. The equations are based in part upon a body of experimental data that has been critically assessed for internal consistency and for agreement with theory whenever possible. We estimate the uncertainty (at the 95% confidence level) for the thermal conductivity of cyclohexane from the triple point (279.86 K) to 650 K at pressures up to 175 MPa to be 4% for the compressed liquid and supercritical phases. For the low-pressure gas phase (up to 0.1 MPa) over the temperature range 280 K to 680 K, the estimated uncertainty is 2.5%. Uncertainties in the critical region are much larger, since the thermal conductivity approaches infinity at the critical point and is very sensitive to small changes in density.

Entities:  

Keywords:  critical phenomena; cyclohexane; reference correlations; thermal conductivity; transport properties

Year:  2017        PMID: 28584386      PMCID: PMC5455799          DOI: 10.1063/1.4974325

Source DB:  PubMed          Journal:  J Phys Chem Ref Data        ISSN: 0047-2689            Impact factor:   2.828


  6 in total

1.  Calculation of the transport properties of carbon dioxide. II. Thermal conductivity and thermomagnetic effects.

Authors:  Steffen Bock; Eckard Bich; Eckhard Vogel; Alan S Dickinson; Velisa Vesovic
Journal:  J Chem Phys       Date:  2004-05-01       Impact factor: 3.488

2.  Crossover from singular to regular behavior of the transport properties of fluids in the critical region.

Authors: 
Journal:  Phys Rev Lett       Date:  1988-07-04       Impact factor: 9.161

3.  Calculation of the transport and relaxation properties of methane. II. Thermal conductivity, thermomagnetic effects, volume viscosity, and nuclear-spin relaxation.

Authors:  Robert Hellmann; Eckard Bich; Eckhard Vogel; Alan S Dickinson; Velisa Vesovic
Journal:  J Chem Phys       Date:  2009-03-28       Impact factor: 3.488

4.  Ab initio intermolecular potential energy surface and thermophysical properties of hydrogen sulfide.

Authors:  Robert Hellmann; Eckard Bich; Eckhard Vogel; Velisa Vesovic
Journal:  Phys Chem Chem Phys       Date:  2011-06-30       Impact factor: 3.676

5.  Reference Correlations of the Thermal Conductivity of Ethene and Propene.

Authors:  M J Assael; A Koutian; M L Huber; R A Perkins
Journal:  J Phys Chem Ref Data       Date:  2016-08-03       Impact factor: 2.828

6.  Reference Correlation of the Thermal Conductivity of Carbon Dioxide from the Triple Point to 1100 K and up to 200 MPa.

Authors:  M L Huber; E A Sykioti; M J Assael; R A Perkins
Journal:  J Phys Chem Ref Data       Date:  2016-02-25       Impact factor: 2.828

  6 in total
  3 in total

1.  Reference Correlations for the Viscosity and Thermal Conductivity of n-Undecane.

Authors:  M J Assael; T B Papalas; M L Huber
Journal:  J Phys Chem Ref Data       Date:  2017-09       Impact factor: 2.828

2.  Correlations for the Viscosity and Thermal Conductivity of Ethyl Fluoride (R161).

Authors:  Ch M Tsolakidou; M J Assael; M L Huber; R A Perkins
Journal:  J Phys Chem Ref Data       Date:  2017-05-17       Impact factor: 2.828

3.  Reference Values and Reference Correlations for the Thermal Conductivity and Viscosity of Fluids.

Authors:  M J Assael; A E Kalyva; S A Monogenidou; M L Huber; R A Perkins; D G Friend; E F May
Journal:  J Phys Chem Ref Data       Date:  2018       Impact factor: 2.828

  3 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.