| Literature DB >> 28580988 |
Shang-Fu Yuan1, Pei Li, Qing Tang, Xian-Kai Wan, Zi-Ang Nan, De-En Jiang, Quan-Ming Wang.
Abstract
Two unique silver nanoclusters protected by alkynyl and diphosphine ligands have been synthesized. Single crystal structural determination reveals that they have a centered anticuboctahedral Ag13 kernel. Such a kernel is observed for the first time in a coinage metal nanocluster. This work offers new insights into the fact that the PhC[triple bond, length as m-dash]C ligand represents a new direction in synthesizing novel metal nanoclusters.Entities:
Year: 2017 PMID： 28580988 DOI： 10.1039/c7nr02687k
Source DB: PubMed Journal: Nanoscale ISSN： 2040-3364 Impact factor: 7.790