Literature DB >> 28576028

Synthesis and characterization of Eu(III) complexes of modified d-glucosamine and poly(N-isopropylacrylamide).

Guihua Cui1, Yu Bai2, Wenliang Li3, Zhengguo Gao4, Shuiying Chen5, Nannan Qiu5, Toshifumi Satoh6, Toyoji Kakuchi5, Qian Duan7.   

Abstract

A series of chain-end functional polymers composed of poly(N-isopropylacrylamide) (PNIPAM) and 2-amino-2-deoxy-d-glucopyranose(d-glucosamine, GA) was synthesized via atom transfer radical polymerization (ATRP). Novel fluorescent complexes of glucosamine-PNI- PAM/Eu(III) were then formed by chelation of the polymers and europium(III) ions. The aqueous solutions of the polymers and its Eu(III) complexes exhibited a lower critical solution temperatures (LCSTs), and which were approximately equal to body temperature. Cell viability assays suggested that these thermosensitive polymers and Eu(III) complexes showed excellent biocompatibility in vitro.
Copyright © 2017. Published by Elsevier B.V.

Entities:  

Keywords:  Atom transfer radical polymerization (ATRP); Fluorescence; Lower critical solution temperature (LCST); Poly(N-isopropylacrylamide) (PNIPAM); d-glucosamine(GA)

Mesh:

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Year:  2017        PMID: 28576028     DOI: 10.1016/j.msec.2017.03.059

Source DB:  PubMed          Journal:  Mater Sci Eng C Mater Biol Appl        ISSN: 0928-4931            Impact factor:   7.328


  2 in total

1.  Eu3+- and Tb3+-Based Coordination Complexes of Poly(N-Isopropyl,N-methylacrylamide-stat-N,N-dimethylacrylamide) Copolymer: Synthesis, Characterization and Property.

Authors:  Jian Li; Guihua Cui; Siyuan Bi; Xu Cui; Yanhui Li; Qian Duan; Toyoji Kakuchi; Yougen Chen
Journal:  Polymers (Basel)       Date:  2022-04-29       Impact factor: 4.967

Review 2.  Hydrogel Adsorbents for the Removal of Hazardous Pollutants-Requirements and Available Functions as Adsorbent.

Authors:  Yoshimi Seida; Hideaki Tokuyama
Journal:  Gels       Date:  2022-04-03
  2 in total

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