Literature DB >> 28573292

Enantioselective incorporation of dicarboxylate guests by octacalcium phosphate.

Taishi Yokoi1, Shingo Machida, Yoshiyuki Sugahara, Masami Hashimoto, Satoshi Kitaoka.   

Abstract

Enantioselectivity by octacalcium phosphate (OCP) is revealed through the incorporation of (S)-(-)-methylsuccinic acid (MeSuc) into its crystal lattice, with hardly any (R)-(+)-MeSuc incorporated. This phenomenon clearly indicates that OCP recognizes the steric structures of guest molecules, extending chiral recognition in inorganic materials to three-dimensional crystal growth.

Entities:  

Year:  2017        PMID: 28573292     DOI: 10.1039/c7cc01169e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

Review 1.  Octacalcium phosphate with incorporated carboxylate ions: a review.

Authors:  Taishi Yokoi; Masaya Shimabukuro; Masakazu Kawashita
Journal:  Sci Technol Adv Mater       Date:  2022-07-20       Impact factor: 7.821

  1 in total

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