Literature DB >> 28570757

Illuminating Iron: Mesoionic Carbenes as Privileged Ligands in Photochemistry.

Biprajit Sarkar1, Lisa Suntrup1.   

Abstract

The new iron age: The stabilization of an iron(III) complex with mesoionic carbenes has been shown to lead to record-breaking excited-state lifetimes and an unprecedented spin-allowed radiative decay from a 2 LMCT state. These results set the stage for a sustainable future in the new "iron age".
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  N-heterocyclic carbenes; iron; mesoionic carbenes; photochemistry; ruthenium

Year:  2017        PMID： 28570757     DOI： 10.1002/anie.201704522

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

Review 1.  Chemistry of Compounds Based on 1,2,3-Triazolylidene-Type Mesoionic Carbenes.

Authors:  Ramananda Maity; Biprajit Sarkar
Journal:  JACS Au       Date:  2021-12-15

2.  Manganese(I) Complex with Monodentate Arylisocyanide Ligands Shows Photodissociation Instead of Luminescence.

Authors:  Sascha Ossinger; Alessandro Prescimone; Daniel Häussinger; Oliver S Wenger
Journal:  Inorg Chem       Date:  2022-06-29       Impact factor: 5.436

3.  Mesoionic Imines (MIIs): Strong Donors and Versatile Ligands for Transition Metals and Main Group Substrates.

Authors:  Richard Rudolf; Nicolás I Neuman; Robert R M Walter; Mark R Ringenberg; Biprajit Sarkar
Journal:  Angew Chem Int Ed Engl       Date:  2022-04-19       Impact factor: 16.823

4.  Mechanistic and Kinetic Investigations of ON/OFF (Photo)Switchable Binding of Carbon Monoxide by Chromium(0), Molybdenum(0) and Tungsten(0) Carbonyl Complexes with a Pyridyl-Mesoionic Carbene Ligand.

Authors:  Pit J Boden; Patrick Di Martino-Fumo; Tobias Bens; Sophie T Steiger; Daniel Marhöfer; Gereon Niedner-Schatteburg; Biprajit Sarkar
Journal:  Chemistry       Date:  2022-07-13       Impact factor: 5.020
  4 in total

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