Aromatic-Imide-Based Thermally Activated Delayed Fluorescence Materials for Highly Efficient Organic Light-Emitting Diodes.

Aromatic-imide-based thermally activated delayed fluorescence (TADF) materials with a twisted donor-acceptor-donor skeleton were efficiently synthesized and exhibited excellent thermal stability and high photoluminescence quantum yields. The small ΔEST value (<0.1 eV) along with the clear temperature-dependent delayed component of their transient photoluminescence (PL) spectra demonstrated their excellent TADF properties. Moreover, the performance of organic light-emitting diodes in which TADF materials AI-Cz and AI-TBCz were used as dopants were outstanding, with external quantum efficiencies up to 23.2 and 21.1 %, respectively.