Literature DB >> 28548663

FLP reactivity of [Ph3C]+ and (o-tolyl)3P and the capture of a Staudinger reaction intermediate.

Jiliang Zhou1, Levy L Cao1, Liu Leo Liu1, Douglas W Stephan1.   

Abstract

The frustrated Lewis pair (FLP) derived from the trityl cation and (o-tolyl)3P effects the activation of 1,4-cyclohexadiene and 1-bromo-4-ethynylbenzene and heterolytically cleaves the S-S bond of diphenyl disulfide. The FLP also captures pentafluorophenyl azide as the Staudinger reaction intermediate, a species that reacts with Ph3SiH to give the silyl analog.

Entities:  

Year:  2017        PMID： 28548663     DOI： 10.1039/c7dt01726j

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  4 in total

1.  Frustrated Lewis Pair Mediated 1,2-Hydrocarbation of Alkynes.

Authors:  Valerio Fasano; Liam D Curless; James E Radcliffe; Michael J Ingleson
Journal:  Angew Chem Int Ed Engl       Date:  2017-07-04       Impact factor: 15.336

2.  The Varied Frustrated Lewis Pair Reactivity of the Germylene Phosphaketene (CH{(CMe)(2,6-i Pr2 C6 H3 N)}2 )GePCO.

Authors:  Yile Wu; Zhao Zhao; Ting Chen; Jingjie Tan; Zheng-Wang Qu; Stefan Grimme; Yufen Zhao; Douglas W Stephan
Journal:  Chemistry       Date:  2022-03-24       Impact factor: 5.020

3.  Metal-Free Phosphination and Continued Functionalization of Pyridine: A Theoretical Study.

Authors:  Pan Du; Yuhao Yin; Dai Shi; Kexin Mao; Qianyuan Yu; Jiyang Zhao
Journal:  Molecules       Date:  2022-09-03       Impact factor: 4.927

4.  New Insights in Frustrated Lewis Pair Chemistry with Azides.

Authors:  Devin H A Boom; Andrew R Jupp; Martin Nieger; Andreas W Ehlers; J Chris Slootweg
Journal:  Chemistry       Date:  2019-09-09       Impact factor: 5.236
  4 in total

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