| Literature DB >> 28544253 |
Abstract
The history and theory of one- and three-electron bonds are presented and discussed. It is shown that the dependence of the odd-electron bond energy on the difference in ionization potentials of the bonding partners must be corrected to include the ion-pairing energy for neutral odd-electron bonded complexes.Keywords: ab initio calculations; bond theory; odd-electron bonds; radical reactions; reactive intermediates
Year: 2017 PMID： 28544253 DOI： 10.1002/cphc.201700417
Source DB: PubMed Journal: Chemphyschem ISSN： 1439-4235 Impact factor: 3.102