Literature DB >> 28539042

Ruthenium-Catalyzed Cycloisomerization of 2-Alkynylanilides: Synthesis of 3-Substituted Indoles by 1,2-Carbon Migration.

Takuma Watanabe1, Yuichiro Mutoh1, Shinichi Saito1.   

Abstract

We developed ruthenium-catalyzed cycloisomerization of alkynylanilides that gave 3-substituted indoles in high yields. The reaction proceeded via the disubstituted vinylidene ruthenium complex that was formed by the 1,2-carbon migration.

Entities:  

Year:  2017        PMID： 28539042     DOI： 10.1021/jacs.7b04564

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  2 in total

1.  Computational study of Ru-catalyzed cycloisomerization of 2-alkynylanilides.

Authors:  Xinghui Zhang; Shanshan Li; Xiaoli Wei; Yun Lei
Journal:  J Mol Model       Date:  2018-06-14       Impact factor: 1.810

2.  Macrolactonization of methyl 15-hydroxypentadecanoate to cyclopentadecanolide using KF-La/γ-Al2O3 catalyst.

Authors:  Haijun Cheng; Chang Yu; Hongyun Wang; Xiongmin Liu; Li Ma; Fang Lai
Journal:  R Soc Open Sci       Date:  2022-09-07       Impact factor: 3.653
  2 in total

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