Literature DB >> 28537399

Palladium-Catalyzed C(sp2)-H Acetoxylation via Electrochemical Oxidation.

Yi-Qian Li1,2, Qi-Liang Yang2, Ping Fang2, Tian-Sheng Mei2, Dayong Zhang1.   

Abstract

Palladium-catalyzed arene C(sp2)-H acetoxylation has emerged as a powerful tool to construct a carbon-oxygen (C-O) bond. However, the requirement of stoichiometric chemical oxidants for this transformation possesses a significant disadvantage. To solve this fundamental problem, we now report an anodic oxidation strategy to achieve arene C(sp2)-H acetoxylation.

Entities:  

Year:  2017        PMID： 28537399     DOI： 10.1021/acs.orglett.7b01138

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  8 in total

1.  Palladium-Catalyzed C-H Bond Acetoxylation via Electrochemical Oxidation.

Authors:  Anuska Shrestha; Melissa Lee; Anna L Dunn; Melanie S Sanford
Journal:  Org Lett       Date:  2017-12-22       Impact factor: 6.005

2.  Synthetic Organic Electrochemical Methods Since 2000: On the Verge of a Renaissance.

Authors:  Ming Yan; Yu Kawamata; Phil S Baran
Journal:  Chem Rev       Date:  2017-10-09       Impact factor: 60.622

3.  Rhoda-Electrocatalyzed Bimetallic C-H Oxygenation by Weak O-Coordination.

Authors:  Xuefeng Tan; Leonardo Massignan; Xiaoyan Hou; Johanna Frey; João C A Oliveira; Masoom Nasiha Hussain; Lutz Ackermann
Journal:  Angew Chem Int Ed Engl       Date:  2021-05-07       Impact factor: 15.336

4.  Azaruthena(II)-bicyclo[3.2.0]heptadiene: Key Intermediate for Ruthenaelectro(II/III/I)-catalyzed Alkyne Annulations.

Authors:  Long Yang; Ralf Steinbock; Alexej Scheremetjew; Rositha Kuniyil; Lars H Finger; Antonis M Messinis; Lutz Ackermann
Journal:  Angew Chem Int Ed Engl       Date:  2020-05-12       Impact factor: 15.336

5.  C-H Oxygenation Reactions Enabled by Dual Catalysis with Electrogenerated Hypervalent Iodine Species and Ruthenium Complexes.

Authors:  Leonardo Massignan; Xuefeng Tan; Tjark H Meyer; Rositha Kuniyil; Antonis M Messinis; Lutz Ackermann
Journal:  Angew Chem Int Ed Engl       Date:  2020-01-09       Impact factor: 15.336

6.  Nickela-electrocatalyzed C-H Alkoxylation with Secondary Alcohols: Oxidation-Induced Reductive Elimination at Nickel(III).

Authors:  Shou-Kun Zhang; Julia Struwe; Lianrui Hu; Lutz Ackermann
Journal:  Angew Chem Int Ed Engl       Date:  2020-01-16       Impact factor: 15.336

7.  Eco-friendly methoximation of aromatic aldehydes and ketones using MnCl2.4H2O as an easily accessible and efficient catalyst.

Authors:  Melina C Ontivero; Teodoro S Kaufman; Iván Cortés; Andrea B J Bracca
Journal:  R Soc Open Sci       Date:  2021-07-28       Impact factor: 2.963

8.  Carboxylate breaks the arene C-H bond via a hydrogen-atom-transfer mechanism in electrochemical cobalt catalysis.

Authors:  Xin-Ran Chen; Shuo-Qing Zhang; Tjark H Meyer; Chun-Hui Yang; Qin-Hao Zhang; Ji-Ren Liu; Hua-Jian Xu; Fa-He Cao; Lutz Ackermann; Xin Hong
Journal:  Chem Sci       Date:  2020-05-19       Impact factor: 9.825
  8 in total

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