Literature DB >> 28537280

A more critical role for silicon in the catalytic Staudinger amidation: silanes as non-innocent reductants.

Keith G Andrews1, Ross M Denton.   

Abstract

A revised pathway for the catalytic Staudinger amidation reaction is presented that involves the intervention of in situ-generated silyl esters as the species responsible for amidation.

Entities:  

Year:  2017        PMID： 28537280     DOI： 10.1039/c7cc03076b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Chemoselective Reduction of Phosphine Oxides by 1,3-Diphenyl-Disiloxane.

Authors:  Joseph A Buonomo; Carter G Eiden; Courtney C Aldrich
Journal:  Chemistry       Date:  2017-09-18       Impact factor: 5.236

2.  CuH-Catalyzed Asymmetric Reductive Amidation of α,β-Unsaturated Carboxylic Acids.

Authors:  Achim Link; Yujing Zhou; Stephen L Buchwald
Journal:  Org Lett       Date:  2020-07-06       Impact factor: 6.005

3.  Main Group Redox Catalysis of Organopnictogens: Vertical Periodic Trends and Emerging Opportunities in Group 15.

Authors:  Jeffrey M Lipshultz; Gen Li; Alexander T Radosevich
Journal:  J Am Chem Soc       Date:  2021-01-19       Impact factor: 15.419

4.  Driving Recursive Dehydration by PIII/PV Catalysis: Annulation of Amines and Carboxylic Acids by Sequential C-N and C-C Bond Formation.

Authors:  Morgan Lecomte; Jeffrey M Lipshultz; Shin-Ho Kim-Lee; Gen Li; Alexander T Radosevich
Journal:  J Am Chem Soc       Date:  2019-07-30       Impact factor: 15.419

5.  Convergent Synthesis of Polysubstituted Furans via Catalytic Phosphine Mediated Multicomponent Reactions.

Authors:  Xia Fan; Rongshun Chen; Jie Han; Zhengjie He
Journal:  Molecules       Date:  2019-12-16       Impact factor: 4.411
  5 in total

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