Literature DB >> 28534398

Enantioselective Synthesis of Isoflavanones by Catalytic Dynamic Kinetic Resolution.

Tao Qin1, Peter Metz1.   

Abstract

A ruthenium-catalyzed asymmetric transfer hydrogenation of racemic isoflavanones with dynamic kinetic resolution yields virtually enantiopure isoflavanols as single diastereomers. Subsequent oxidation gives rise to isoflavanones in high enantiomeric purities.

Entities:  

Year:  2017        PMID： 28534398     DOI： 10.1021/acs.orglett.7b01218

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Enantioselective Synthesis of Homoisoflavanones by Asymmetric Transfer Hydrogenation and Their Biological Evaluation for Antiangiogenic Activity.

Authors:  Myunghoe Heo; Bit Lee; Kamakshi Sishtla; Xiang Fei; Sanha Lee; Soojun Park; Yue Yuan; Seul Lee; Sangil Kwon; Jungeun Lee; Sanghee Kim; Timothy W Corson; Seung-Yong Seo
Journal:  J Org Chem       Date:  2019-08-05       Impact factor: 4.354

2.  Asymmetric one-pot transformation of isoflavones to pterocarpans and its application in phytoalexin synthesis.

Authors:  Philipp Ciesielski; Peter Metz
Journal:  Nat Commun       Date:  2020-06-18       Impact factor: 14.919

3.  Total Synthesis of Naturally Occurring 5,7,8-Trioxygenated Homoisoflavonoids.

Authors:  Sangil Kwon; Sanha Lee; Myunghoe Heo; Bit Lee; Xiang Fei; Timothy W Corson; Seung-Yong Seo
Journal:  ACS Omega       Date:  2020-05-06
  3 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.