What Do Laser-Induced Transient Techniques Reveal for Batteries? Na- and K-Intercalation from Aqueous Electrolytes as an Example.

Technological advancement has been revolutionized by rechargeable batteries, without which the use of various modern devices would not be possible. Aqueous Na ion batteries have lately garnered much attention, being recognized as a promising alternative to the commonly used Li ion batteries for the large-scale energy storage systems. However, further improvement and optimization of such systems require a more detailed understanding of intercalation mechanisms. In this work, we for the first time demonstrate the implementation of the laser-induced current transient (LICT) technique for in situ characterization of battery systems and investigate the interface between Na2Ni[Fe(CN)6] model battery electrodes and aqueous electrolytes in contact with aqueous electrolytes. Quite counterintuitively, the LICT method revealed that at the quasi-steady-state the electrode surface stays positively charged within the potential range where the intercalation/deintercalation of sodium as well as of potassium is possible, evidencing that the intercalation mechanism of the alkali-metal cations should be rather complex. Furthermore, the specific shape of the observed current transients indicates that the interfacial processes of intercalation/deintercalation have at least three different relaxation time constants. The relaxation behavior is highly influenced by the nature of the alkali-metal cations-most likely through their different solvation energy. In addition, we outline how the laser-based experiments can intensify detailed in situ investigations of battery systems.