Literature DB >> 28525275

Rh-Catalyzed Anti-Markovnikov Hydrocyanation of Terminal Alkynes.

Fei Ye1, Junting Chen1, Tobias Ritter1.   

Abstract

We report the first highly stereo- and regioselective hydrocyanation of terminal alkynes to furnish E-configured alkenyl nitriles. Acrylonitriles can be accessed on gram scale with broad substrate scope and functional group tolerance. The hydrocyanation reaction employs acetone cyanohydrin as a practical alternative to HCN gas.

Entities:  

Year:  2017        PMID： 28525275     DOI： 10.1021/jacs.7b03749

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  8 in total

1.  Direct Access to Versatile Electrophiles via Catalytic Oxidative Cyanation of Alkenes.

Authors:  De-Wei Gao; Ekaterina V Vinogradova; Sri Krishna Nimmagadda; Jose M Medina; Yiyang Xiao; Radu M Suciu; Benjamin F Cravatt; Keary M Engle
Journal:  J Am Chem Soc       Date:  2018-06-22       Impact factor: 15.419

2.  Remote Oxidative Activation of a [Cp*Rh] Monohydride.

Authors:  Emily A Boyd; Julie A Hopkins Leseberg; Emma L Cosner; Davide Lionetti; Wade C Henke; Victor W Day; James D Blakemore
Journal:  Chemistry       Date:  2022-02-03       Impact factor: 5.236

Review 3.  Direct cyanation, hydrocyanation, dicyanation and cyanofunctionalization of alkynes.

Authors:  Lifen Peng; Zhifang Hu; Hong Wang; Li Wu; Yinchun Jiao; Zilong Tang; Xinhua Xu
Journal:  RSC Adv       Date:  2020-03-10       Impact factor: 4.036

4.  Metal-Free Direct C-H Cyanation of Alkenes.

Authors:  Xi Wang; Armido Studer
Journal:  Angew Chem Int Ed Engl       Date:  2018-08-06       Impact factor: 15.336

5.  E- and Z-, di- and tri-substituted alkenyl nitriles through catalytic cross-metathesis.

Authors:  Yucheng Mu; Thach T Nguyen; Ming Joo Koh; Richard R Schrock; Amir H Hoveyda
Journal:  Nat Chem       Date:  2019-04-01       Impact factor: 24.427

6.  Cyano-borrowing reaction: nickel-catalyzed direct conversion of cyanohydrins and aldehydes/ketones to β-cyano ketone.

Authors:  Zhao-Feng Li; Qian Li; Li-Qing Ren; Qing-Hua Li; Yun-Gui Peng; Tang-Lin Liu
Journal:  Chem Sci       Date:  2019-05-06       Impact factor: 9.825

7.  DFT calculations bring insight to internal alkyne-to-vinylidene transformations at rhodium PNP- and PONOP-pincer complexes.

Authors:  Nasir A Rajabi; Claire L McMullin
Journal:  RSC Adv       Date:  2021-03-23       Impact factor: 3.361

Review 8.  Application of Coordination Compounds with Transition Metal Ions in the Chemical Industry-A Review.

Authors:  Jacek Malinowski; Dominika Zych; Dagmara Jacewicz; Barbara Gawdzik; Joanna Drzeżdżon
Journal:  Int J Mol Sci       Date:  2020-07-30       Impact factor: 5.923
  8 in total

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