Literature DB >> 28524922

3,4-Alkadienyl ketones via the palladium-catalyzed decarboxylative allenylation of 3-oxocarboxylic acids.

Tonghao Zhu1, Shengming Ma.   

Abstract

In this communication, we report a palladium-catalyzed decarboxylative allenylation of benzyl carbonates and tert-butyl carbonates of 2,3-allenols with 3-oxocarboxylic acids. The reaction provides a new and straightforward approach to 3,4-dienyl ketones under mild conditions.

Entities:  

Year:  2017        PMID: 28524922     DOI: 10.1039/c7cc02050c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Catalytic enantioselective construction of axial chirality in 1,3-disubstituted allenes.

Authors:  Shihua Song; Jing Zhou; Chunling Fu; Shengming Ma
Journal:  Nat Commun       Date:  2019-01-31       Impact factor: 14.919

  1 in total

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