Literature DB >> 2851985

The nature of the phosphate complex of sulphite oxidase from electron-paramagnetic-resonance studies.

G N George1, R C Prince, C A Kipke, R A Sunde, J H Enemark.   

Abstract

The phosphate complex of sulphite oxidase in the Mo(V) oxidation state was investigated by e.p.r. spectroscopy. Third-derivative spectra reveal a wealth of structural detail previously unobserved in this spectrum. Most notable is the presence of hyperfine coupling from two inequivalent I = 1/2 nuclei, which we tentatively attribute to two 31P nuclei. Unresolved hyperfine interactions from at least one exchangeable 1H nucleus are also present.

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Year:  1988        PMID: 2851985      PMCID: PMC1135405          DOI: 10.1042/bj2560307

Source DB:  PubMed          Journal:  Biochem J        ISSN: 0264-6021            Impact factor:   3.857


  9 in total

1.  Studies by electron paramagnetic resonance spectroscopy of xanthine oxidase enriched with molybdenum-95 and with molybdenum-97.

Authors:  G N George; R C Bray
Journal:  Biochemistry       Date:  1988-05-17       Impact factor: 3.162

Review 2.  The inorganic biochemistry of molybdoenzymes.

Authors:  R C Bray
Journal:  Q Rev Biophys       Date:  1988-08       Impact factor: 5.318

3.  Purification and properties of sulfite oxidase from chicken liver. Presence of molybdenum in sulfite oxidase from diverse sources.

Authors:  D L Kessler; K V Rajagopalan
Journal:  J Biol Chem       Date:  1972-10-25       Impact factor: 5.157

4.  Hepatic sulfite oxidase. Effect of anions on interaction with cytochrome c.

Authors:  D L Kessler; K V Rajagopalan
Journal:  Biochim Biophys Acta       Date:  1974-12-29

5.  The nature of the phosphate inhibitor complex of sulphite oxidase from electron-paramagnetic-resonance studies using oxygen-17.

Authors:  S Gutteridge; M T Lamy; R C Bray
Journal:  Biochem J       Date:  1980-10-01       Impact factor: 3.857

Review 6.  The reactions and the structures of molybdenum centers in enzymes.

Authors:  R C Bray
Journal:  Adv Enzymol Relat Areas Mol Biol       Date:  1980

7.  The pterin component of the molybdenum cofactor. Structural characterization of two fluorescent derivatives.

Authors:  J L Johnson; B E Hainline; K V Rajagopalan; B H Arison
Journal:  J Biol Chem       Date:  1984-05-10       Impact factor: 5.157

8.  Electron-paramagnetic-resonance parameters of molybdenum(V) in sulphite oxidase from chicken liver.

Authors:  M T Lamy; S Gutteridge; R C Bary
Journal:  Biochem J       Date:  1980-02-01       Impact factor: 3.857

9.  Equilibria amongst different molybdenum (V)-containing species from sulphite oxidase. Evidence for a halide ligand of molybdenum in the low-pH species.

Authors:  R C Bray; S Gutteridge; M T Lamy; T Wilkinson
Journal:  Biochem J       Date:  1983-04-01       Impact factor: 3.857

  9 in total
  3 in total

1.  MoV electron paramagnetic resonance of sulfite oxidase revisited: the low-pH chloride signal.

Authors:  Christian J Doonan; Heather L Wilson; Brian Bennett; Roger C Prince; K V Rajagopalan; Graham N George
Journal:  Inorg Chem       Date:  2008-02-14       Impact factor: 5.165

2.  Applications of pulsed EPR spectroscopy to structural studies of sulfite oxidizing enzymes().

Authors:  Eric L Klein; Andrei V Astashkin; Arnold M Raitsimring; John H Enemark
Journal:  Coord Chem Rev       Date:  2013-01-01       Impact factor: 22.315

3.  E.p.r.-spectroscopic studies on the molybdenum-iron site of nitrogenase from Clostridium pasteurianum.

Authors:  G N George; R E Bare; H Y Jin; E I Stiefel; R C Prince
Journal:  Biochem J       Date:  1989-08-15       Impact factor: 3.857

  3 in total

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