Literature DB >> 28503682

Hydroboration of alkynes and nitriles using an α-diimine cobalt hydride catalyst.

Hagit Ben-Daat1, Christopher L Rock, Marco Flores, Thomas L Groy, Amanda C Bowman, Ryan J Trovitch.   

Abstract

Addition of NaEt3BH to (Ph2PPrDI)CoCl2 affords the corresponding monohydride, (Ph2PPrDI)CoH. X-ray diffraction and DFT calculations indicate that this compound possesses a radical monoanion α-DI chelate and a Co(ii) centre. Notably, (Ph2PPrDI)CoH catalyzes the hydroboration of alkynes and dihydroboration of nitriles under mild conditions.

Entities:  

Year:  2017        PMID： 28503682     DOI： 10.1039/c7cc02281f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

1.  Solvent-free hydroboration of alkynes catalyzed by an NHC-cobalt complex.

Authors:  Małgorzata Bołt; Patrycja Żak
Journal:  RSC Adv       Date:  2022-06-27       Impact factor: 4.036

Review 2.  Emergence and Applications of Base Metals (Fe, Co, and Ni) in Hydroboration and Hydrosilylation.

Authors:  Sem Raj Tamang; Michael Findlater
Journal:  Molecules       Date:  2019-09-03       Impact factor: 4.411

3.  Highly Chemoselective Hydroboration of Alkynes and Nitriles Catalyzed by Group 4 Metal Amidophosphine-Borane Complexes.

Authors:  Jayeeta Bhattacharjee; Adimulam Harinath; Kulsum Bano; Tarun K Panda
Journal:  ACS Omega       Date:  2020-01-10

4.  Reaction Pathways and Redox States in α-Selective Cobalt-Catalyzed Hydroborations of Alkynes.

Authors:  Clemens K Blasius; Vladislav Vasilenko; Regina Matveeva; Hubert Wadepohl; Lutz H Gade
Journal:  Angew Chem Int Ed Engl       Date:  2020-10-15       Impact factor: 15.336

5.  Iron-catalysed hydroboration of non-activated imines and nitriles: kinetic and mechanistic studies.

Authors:  Adineh Rezaei Bazkiaei; Michael Wiseman; Michael Findlater
Journal:  RSC Adv       Date:  2021-04-23       Impact factor: 3.361

6.  Hydroboration of nitriles and imines by highly active zinc dihydride catalysts.

Authors:  Xiaoming Wang; Xin Xu
Journal:  RSC Adv       Date:  2021-01-04       Impact factor: 3.361

7.  Alkene hydroboration with pinacolborane catalysed by lithium diisobutyl-tert-butoxyaluminum hydride.

Authors:  Ashok Kumar Jaladi; Won Kyu Shin; Duk Keun An
Journal:  RSC Adv       Date:  2019-08-23       Impact factor: 3.361
  7 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.