Literature DB >> 28501150

Facile one-pot fabrication of Ag@MOF(Ag) nanocomposites for highly selective detection of 2,4,6-trinitrophenol in aqueous phase.

Hongxu Guo1, Yanhui Zhang2, Zishan Zheng2, Haibin Lin2, Yi Zhang2.   

Abstract

Ag@MOF(Ag) nano-composites were fabricated through one-pot facile reflux reaction from the raw materials of AgNO3 and 2-aminoterephthalic acid, and were then characterized through SEM, TEM, XRD, XPS, and FTIR, which showed a high fluorescence quantum yield (10.6%) and exhibited outstanding selectivity and excellent sensitivity for 2,4,6-trinitrophenol (TNP) over a concentration range of 1-29μM in water. The fluorescence quenching mechanism may be attributed to hydrogen-bonding interactions and resonance energy transfer.
Copyright © 2017 Elsevier B.V. All rights reserved.

Entities:  

Keywords:  2, 4, 6-trinitrophenol; Ag@MOF(Ag); Facile reflux reaction; Fluorescence sensor; Nano-composites

Year:  2017        PMID: 28501150     DOI: 10.1016/j.talanta.2017.03.096

Source DB:  PubMed          Journal:  Talanta        ISSN: 0039-9140            Impact factor:   6.057


  9 in total

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9.  A new silver coordination polymer based on 4,6-diamino-2-pyrimidinethiol: synthesis, characterization and catalytic application in asymmetric Hantzsch synthesis of polyhydroquinolines.

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  9 in total

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