| Literature DB >> 28489351 |
Andrés García-Domínguez1, Zhaodong Li1, Cristina Nevado1.
Abstract
An intermolecular, three-component reductive dicarbofunctionalization of alkenes is presented here. The combination of Ni catalysis with TDAE as final reductant enables the direct formation of Csp3-Csp3 and Csp3-Csp2 bonds across a variety of π-systems using two different electrophiles that are sequentially activated with exquisite selectivity under mild reaction conditions.Entities:
Year: 2017 PMID: 28489351 DOI: 10.1021/jacs.7b03195
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419