Literature DB >> 28485450

A room temperature cyanation of (hetero)aromatic chlorides by an air stable nickel(ii) XantPhos precatalyst and Zn(CN)2.

D Dawson Beattie1, Thomas Schareina, Matthias Beller.   

Abstract

A methodology for the synthesis of (hetero)aromatic nitriles from aryl chlorides at room temperature has been developed. This methodology uses an air and moisture stable nickel(ii) XantPhos precatalyst and Zn(CN)2 as the cyanide (CN-) source.

Entities:  

Year:  2017        PMID: 28485450     DOI: 10.1039/c7ob00892a

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN: 1477-0520            Impact factor:   3.876


  1 in total

1.  Cu(OAc)2 catalysed aerobic oxidation of aldehydes to nitriles under ligand-free conditions.

Authors:  Asit Kumar Das; Sneha Nandy; Sanjay Bhar
Journal:  RSC Adv       Date:  2022-02-04       Impact factor: 3.361

  1 in total

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