| Literature DB >> 28482662 |
Sheng Zhang1, Jinfang Cai1, Yoshinori Yamamoto1,2, Ming Bao1.
Abstract
Palladium-catalyzed remote sp2-sp3 coupling reaction of chloromethylarenes with allyltrimethoxysilane is described in this work. The allylation reaction regioselectively occurred on the para-positions of 1-(chloromethyl)naphthalenes and benzyl chlorides to form new C(sp2)-C(sp3) bonds. The reaction proceeds smoothly under mild conditions to produce allyl arenes in moderate to excellent yields.Entities:
Year: 2017 PMID： 28482662 DOI： 10.1021/acs.joc.7b00678
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354