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Literature DB >> 28474796

Air-Stable Manganese(I)-Catalyzed C-H Activation for Decarboxylative C-H/C-O Cleavages in Water.

Hui Wang¹, Mélanie M Lorion¹, Lutz Ackermann¹.

Abstract

The decarboxylative C-H/C-O functionalization was accomplished by air- and water-tolerant manganese(I) catalysis. The versatile C-H allylation occurred by facile organometallic C-H metalation on indoles, arenes, amino acids and synthetically meaningful aryl ketimines with ample substrate scope and high levels of chemo-, site- and regio-selectivity.

Entities: Chemical

Keywords: C−H activation; C−O cleavage; amino acids; heterocycles; imines; manganese

Mesh：

Substances：

Year: 2017 PMID： 28474796 DOI： 10.1002/anie.201702193

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

7 in total

1. Ruthenium-Catalyzed C-H Allylation of Alkenes with Allyl Alcohols via C-H Bond Activation in Aqueous Solution.

Authors: Xiaowei Wu; Haitao Ji
Journal: J Org Chem Date: 2018-09-21 Impact factor: 4.354

2. Late-stage ortho-C-H alkenylation of 2-arylindazoles in aqueous medium by Manganese(i)-catalysis.

Authors: Krishna Kanta Das; Asim Kumar Ghosh; Alakananda Hajra
Journal: RSC Adv Date: 2022-07-04 Impact factor: 4.036

Review 3. A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

Authors: Carlo Sambiagio; David Schönbauer; Remi Blieck; Toan Dao-Huy; Gerit Pototschnig; Patricia Schaaf; Thomas Wiesinger; Muhammad Farooq Zia; Joanna Wencel-Delord; Tatiana Besset; Bert U W Maes; Michael Schnürch
Journal: Chem Soc Rev Date: 2018-08-28 Impact factor: 54.564

Air-Stable Manganese(I)-Catalyzed C-H Activation for Decarboxylative C-H/C-O Cleavages in Water.

1. Ruthenium-Catalyzed C-H Allylation of Alkenes with Allyl Alcohols via C-H Bond Activation in Aqueous Solution.

2. Late-stage ortho-C-H alkenylation of 2-arylindazoles in aqueous medium by Manganese(i)-catalysis.

Review 3. A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

Review 4. C4-H indole functionalisation: precedent and prospects.

5. Nickel-catalyzed asymmetric reductive aryl-allylation of unactivated alkenes.

6. Iridium-Catalyzed Enantioselective Intermolecular Indole C2-Allylation.

Review 7. Stapled Peptides-A Useful Improvement for Peptide-Based Drugs.