Literature DB >> 28466276

Ratiometric Detection of Water in Acetonitrile with 9-Hydroxybenzo[b]Quinolizinium as Fluorosolvatochromic Probe.

Katy Schäfer1,2, Heiko Ihmels3,4.   

Abstract

The solvatochromic 9-hydroxybenzo[b]quinolizinium ion is shown to operate as fluorescent probe for the detection of water in acetonitrile. The dual fluorescence of this photoacid and its dependence on the content of water in the medium enable the ratiometric analysis of the fluorescence data. Graphical Abstract ᅟ.

Entities:  

Keywords:  Chemosensors; Fluorescent probes; Fluorimetric water detection

Year:  2017        PMID: 28466276     DOI: 10.1007/s10895-017-2107-1

Source DB:  PubMed          Journal:  J Fluoresc        ISSN: 1053-0509            Impact factor:   2.217


  8 in total

1.  Optical determination of low-level water concentrations in organic solvents using fluorescent acridinyl dyes and dye-immobilized polymer membranes.

Authors:  D Citterio; T K Minamihashi; Y Kuniyoshi; H Hisamoto; S Sasaki; K Suzuki
Journal:  Anal Chem       Date:  2001-11-01       Impact factor: 6.986

2.  Fluorescence water sensor based on covalent immobilization of chalcone derivative.

Authors:  Cheng-Gang Niu; Ai-Ling Guan; Guang-Ming Zeng; Yun-Guo Liu; Zhong-Wu Li
Journal:  Anal Chim Acta       Date:  2006-06-27       Impact factor: 6.558

3.  Validation of a gas chromatography/thermal conductivity detection method for the determination of the water content of oxygenated solvents.

Authors:  W K O'Keefe; F T T Ng; G L Rempel
Journal:  J Chromatogr A       Date:  2007-12-23       Impact factor: 4.759

4.  A novel cascade strategy with supramolecular and chemodosimetric methods for designing a fluorescent ratiometric detector hypersensitive to trace water.

Authors:  Guangwen Men; Chunrong Chen; Chunshuang Liang; Wenkun Han; Shimei Jiang
Journal:  Analyst       Date:  2015-08-21       Impact factor: 4.616

5.  Hydroxybenzo[b]quinolizinium Ions: Water-Soluble and Solvatochromic Photoacids.

Authors:  Katy Schäfer; Heiko Ihmels; Cornelia Bohne; Karolina Papera Valente; Anton Granzhan
Journal:  J Org Chem       Date:  2016-11-01       Impact factor: 4.354

6.  Novel benzo[b]quinolizinium cations as uncompetitive N-methyl-D-aspartic acid (NMDA) antagonists: the relationship between log D and agonist independent (closed) NMDA channel block.

Authors:  W G Earley; V Kumar; J P Mallamo; C Subramanyam; J A Dority; M S Miller; D L DeHaven-Hudkins; L D Aimone; M D Kelly; B Ault
Journal:  J Med Chem       Date:  1995-09-01       Impact factor: 7.446

7.  Recent Advances in the Synthesis of Azonia Aromatic Heterocycles.

Authors:  David Sucunza; Ana M Cuadro; Julio Alvarez-Builla; Juan J Vaquero
Journal:  J Org Chem       Date:  2016-07-18       Impact factor: 4.354

8.  Excited-state acidity of the 8-hydroxyacridizinium ion-a water-soluble photoacid.

Authors:  Heiko Ihmels; Katya Schäfer
Journal:  Photochem Photobiol Sci       Date:  2009-01-19       Impact factor: 3.982

  8 in total
  2 in total

1.  7-Dialkylaminocoumarin Oximates: Small Molecule Fluorescent "Turn-On" Chemosensors for Low-Level Water Content in Aprotic Organic Solvents.

Authors:  Marek Cigáň; Miroslav Horváth; Juraj Filo; Klaudia Jakusová; Jana Donovalová; Vladimír Garaj; Anton Gáplovský
Journal:  Molecules       Date:  2017-08-12       Impact factor: 4.411

2.  Cation-induced ring-opening and oxidation reaction of photoreluctant spirooxazine-quinolizinium conjugates.

Authors:  Phil M Pithan; Sören Steup; Heiko Ihmels
Journal:  Beilstein J Org Chem       Date:  2020-05-05       Impact factor: 2.883

  2 in total

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