Literature DB >> 28462977

Exposure to air boosts CuAAC reactions catalyzed by PEG-stabilized Cu nanoparticles.

Fangyu Fu1, Angel Martinez, Changlong Wang, Roberto Ciganda, Luis Yate, Ane Escobar, Sergio Moya, Eric Fouquet, Jaime Ruiz, Didier Astruc.   

Abstract

New PEG-stabilized CuNP catalysts are designed upon Cu(ii) reduction with sodium naphthalenide in MeCN followed by simple purification using the salting-out effect. Their catalytic activity in CuAAC is boosted upon 30 min exposure to air, producing Cu2O NPs. These NPs are also supported on SBA-15, providing excellent recyclable heterogeneous catalysts that are applied in low amounts for efficient "click" functionalization.

Entities:  

Year:  2017        PMID: 28462977     DOI: 10.1039/c7cc02504a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

Review 1.  Recent Progress of Cu-Catalyzed Azide-Alkyne Cycloaddition Reactions (CuAAC) in Sustainable Solvents: Glycerol, Deep Eutectic Solvents, and Aqueous Media.

Authors:  Noel Nebra; Joaquín García-Álvarez
Journal:  Molecules       Date:  2020-04-26       Impact factor: 4.411

2.  New Acetamidine Cu(II) Schiff base complex supported on magnetic nanoparticles pectin for the synthesis of triazoles using click chemistry.

Authors:  Hossein Khashei Siuki; Pouya Ghamari Kargar; Ghodsieh Bagherzade
Journal:  Sci Rep       Date:  2022-03-08       Impact factor: 4.379

  2 in total

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