Development of smart colourimetric starch-based indicator for liberated volatiles during durian ripeness.

The mechanical, physical and barrier properties of colourimetric starch-based films (CSBFs) were developed by adding natural polymers (chitosan, citric acid, carboxymethylcellulose, and kraft fibre). Novel volatile compound indicator films were prepared from starch (as a film matrix with 30% w/w sorbitol) using the casting method and adding natural polymers, and pH-dye (methyl red and bromothymol blue as indicators). CSBFs mixed with 0.1% chitosan improved the mechanical and barrier properties with a significant decrease in water vapour transmission rate, water solubility, and oxygen transmission rate, as well as improved tensile strength. Trials using liberated fruit aromas verified that CSBFs resulted in visible colour changes in the presence of mixed sulphur and ethyl alcohol aromas. Colour change in terms of the total colour difference of CSBFs was related to mixed sulphur and ethyl alcohol levels, thereby enabling CSBFs could be used to monitor real-time ripeness of durian volatiles.