Cobalt nanoparticles supported on N-doped mesoporous carbon as a highly efficient catalyst for the synthesis of aromatic amines.

Inexpensive and reusable transition metal heterogeneous catalysts exhibiting excellent catalytic performance represent an attractive alternative to noble metal and homogeneous catalysts. In this work, we fabricated a novel nanocatalyst comprised of Co nanoparticles (NPs) supported on a N-doped mesoporous carbon (Co/mCN-900) by simple one-pot pyrolysis of a homogeneous mixture of melamine, polyacrylonitrile, and Co(NO3)2·6H2O under a N2 atmosphere at 900°C. The as-obtained Co/mCN-900 catalyst displayed a fluffy mesoporous structure with highly dispersed and accessible Co NPs acting as catalytic active sites. The Co/mCN-900 catalyst was effective in hydrogenating nitroarenes at milder conditions (i.e., 1MPa H2 and 120°C) as compared to previously reported Co- and Ni-based catalysts. The Co/mCN-900 catalyst also catalyzed the reductive N-alkylation of nitroarenes with carbonyl compounds to form the corresponding aromatic secondary amines under very mild reaction conditions. In addition, the Co/mCN-900 catalyst showed good reusability since its morphology and activity were maintained after several reaction cycles. Therefore, this work provides a facile and promising method for fabricating non-precious transition metal-based catalysts with excellent performance and great potential for sustainable chemistry applications.