Sources and distribution of polycyclic aromatic hydrocarbons (PAHs) and organic matter in surface sediments of an estuary under petroleum activity influence, Todos os Santos Bay, Brazil.

The present study evaluated the origin and distribution of polycyclic aromatic hydrocarbons (PAHs) and the organic matter (OM) in the surface sediment of the São Paulo River estuary, Todos os Santos Bay (TSB), Brazil. The samples were collected in the rainy (CP1) and the dry (CP2) seasons. We analyzed the 16 PAHs from the United States Environmental Protection Agency (US EPA) priority pollutant list, total organic carbon (TOC), total nitrogen (N), and stable carbon isotope (δ13C). The total concentration of PAHs ranged from 11.45±1.28 to 1825.35±107.96ngg-1, while TOC ranged from 3.8 to 27.7gkg-1. CP1 showed the highest concentrations for all parameters. The δ13C ratio indicated terrigenous OM (-23.81 to -26.63‰). The TOC/N ratio (C/N) indicated transitional OM (12.32 to 24.39), in addition to the continental origin. The diagnostic ratios of PAHs origin revealed only pyrolytic source, although close to areas with a history of petroleum contamination.