| Literature DB >> 28447800 |
Matthew V Vollmer1, Jing Xie1, Connie C Lu1.
Abstract
A triad of d10 cobalt dihydrogen complexes was synthesized by utilizing Lewis acidic group 13 metalloligands, M[N((o-C6H4)NCH2PiPr2)3], where M = Al, Ga, and In. These complexes have formal Co(-I) oxidation states, representing the only coordination complexes in which dihydrogen is bound to a subvalent transition metal center. Single-crystal X-ray diffraction and NMR studies support the assignment of these complexes as nonclassical dihydrogen adducts of Co(-I).Entities:
Year: 2017 PMID： 28447800 DOI： 10.1021/jacs.7b02870
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419