Literature DB >> 28447183

Optical and Photophysical Investigation of (2E)-1-(2,5-Dimethylfuran-3-Yl)-3-(9-Ethyl-9H-Carbazol-3-Yl)Prop-2-en-1-One (DEPO) by Spectrofluorometer in Organized Medium.

Abdullah M Asiri1,2, Al-Anood M Al-Dies1, Salman A Khan3.   

Abstract

(2E)-1-(2,5-dimethylfuran-3-yl)-3-(9-ethyl-9H-carbazol-3-yl)prop-2-en-1-one (DEPO) was prepared by the reaction of 9-ethyl-9H-carbazole-3-carbaldehyde with 1-(2,5-dimethylfuran-3-yl)ethanone under microwave irradiation. The structure of DEPO was established experimentally by EI-MS, FT-IR, 1H and 13C NMR spectral studies. Electronic absorption and emission spectra of DEPO were studied in different solvents on the basis of polarities, and the obtain data were used to determine the solvatochromic properties such as extinction coefficient, oscillator strength, transition dipole moment, stokes shift, fluorescence quantum yield and photochemical quantum yield. Photochemical quantum yield (Φ c ) of DEPO dye was determined in different solvent. The dye comparatively photostable in DMSO but undergoes photodecomposition in chloro methane solvents. The DEPO dye may be use as probe or quencher to determine critical micelle concentration (CMC) of cetyltri methyl ammonium bromide (CTAB) and sodium dodecyl sulfate (SDS).

Entities:  

Keywords:  Chalcone; Fluorescence quantum yield; Photochemical quantum yield; Photophysical

Year:  2017        PMID: 28447183     DOI: 10.1007/s10895-017-2088-0

Source DB:  PubMed          Journal:  J Fluoresc        ISSN: 1053-0509            Impact factor:   2.217


  9 in total

1.  Physicochemical and Critical Micelle Concentration (CMC) of Cationic (CATB) and Anionic (SDS) Surfactants with Environmentally Benign Blue Emitting TTQC Dye.

Authors:  Salman A Khan; Abdullah M Asiri
Journal:  J Fluoresc       Date:  2015-09-04       Impact factor: 2.217

2.  TD-DFT study on the excited-state proton transfer in the fluoride sensing of a turn-off type fluorescent chemosensor based on anthracene derivatives.

Authors:  Ping Song; Jun-Xia Ding; Tian-Shu Chu
Journal:  Spectrochim Acta A Mol Biomol Spectrosc       Date:  2012-07-16       Impact factor: 4.098

3.  Estimation of the ground and the first excited singlet-state dipole moments of 1,4-disubstituted anthraquinone dyes by the solvatochromic method.

Authors:  B Siddlingeshwar; S M Hanagodimath
Journal:  Spectrochim Acta A Mol Biomol Spectrosc       Date:  2009-12-06       Impact factor: 4.098

4.  Multi-photon absorption effect and intra-molecular charge transfer of donor-π-acceptor chromophore ethyl p-amino benzoate.

Authors:  D Sajan; N Vijayan; K Safakath; Reji Philip; M Karabacak
Journal:  Spectrochim Acta A Mol Biomol Spectrosc       Date:  2013-02-08       Impact factor: 4.098

5.  Physicochemical Investigation of 2,4,5-Trimethoxybenzylidene Propanedinitrile (TMPN) Dye as Fluorescence off-on Probe for Critical Micelle Concentration (CMC) of SDS and CTAB.

Authors:  Salman A Khan; Abdullah M Asiri
Journal:  J Fluoresc       Date:  2015-10-19       Impact factor: 2.217

6.  Effect of Donor-Acceptor Coupling on TICT Dynamics in the Excited States of Two Dimethylamine Substituted Chalcones.

Authors:  Rajib Ghosh; Dipak K Palit
Journal:  J Phys Chem A       Date:  2015-10-29       Impact factor: 2.781

7.  Unusually high fluorescence quantum yield of a homopolyfluorenylazomethine--towards a universal fluorophore.

Authors:  Charlotte Mallet; Andréanne Bolduc; Sophie Bishop; Yohan Gautier; W G Skene
Journal:  Phys Chem Chem Phys       Date:  2014-11-28       Impact factor: 3.676

8.  A push-pull aromatic chromophore with a touch of merocyanine.

Authors:  Peter D Zoon; Albert M Brouwer
Journal:  Photochem Photobiol Sci       Date:  2009-02-16       Impact factor: 3.982

9.  Synthesis and anti-bacterial activities of a bis-chalcone derived from thiophene and its bis-cyclized products.

Authors:  Abdullah M Asiri; Salman A Khan
Journal:  Molecules       Date:  2011-01-12       Impact factor: 4.411

  9 in total

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