Literature DB >> 28443927

Direct oxidation of the C(sp2)-C(sp3) bond from benzyltrimethylsilanes to phenols.

Wei Li1, Guolin Gao, Yuan Gao, Chao Yang, Wujiong Xia.   

Abstract

A novel pathway for direct conversion of benzylsilanes to phenols by oxidation with Na2S2O8 and oxygen is efficiently developed under mild and neutral conditions. The reaction shows good functional group tolerance to afford phenols in moderate yields. The possible mechanism is proposed based on the isotopic labeling trials.

Entities:  

Year:  2017        PMID: 28443927     DOI: 10.1039/c7cc01868a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Lewis Basic Salt-Promoted Organosilane Coupling Reactions with Aromatic Electrophiles.

Authors:  Tyler W Reidl; Jeffrey S Bandar
Journal:  J Am Chem Soc       Date:  2021-07-27       Impact factor: 16.383

  1 in total

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