Literature DB >> 28439003

Numerical evidence for thermally induced monopoles.

Peter Wirnsberger1, Domagoj Fijan2,3, Roger A Lightwood1, Anđela Šarić1,3, Christoph Dellago4, Daan Frenkel5.   

Abstract

Electric charges are conserved. The same would be expected to hold for magnetic charges, yet magnetic monopoles have never been observed. It is therefore surprising that the laws of nonequilibrium thermodynamics, combined with Maxwell's equations, suggest that colloidal particles heated or cooled in certain polar or paramagnetic solvents may behave as if they carry an electric/magnetic charge. Here, we present numerical simulations that show that the field distribution around a pair of such heated/cooled colloidal particles agrees quantitatively with the theoretical predictions for a pair of oppositely charged electric or magnetic monopoles. However, in other respects, the nonequilibrium colloidal particles do not behave as monopoles: They cannot be moved by a homogeneous applied field. The numerical evidence for the monopole-like fields around heated/cooled colloidal particles is crucial because the experimental and numerical determination of forces between such colloidal particles would be complicated by the presence of other effects, such as thermophoresis.

Keywords:  colloids; molecular simulation; monopoles; nonequilibrium thermodynamics; soft matter

Year:  2017        PMID: 28439003      PMCID: PMC5441697          DOI: 10.1073/pnas.1621494114

Source DB:  PubMed          Journal:  Proc Natl Acad Sci U S A        ISSN: 0027-8424            Impact factor:   11.205


  13 in total

1.  Thermomolecular orientation of nonpolar fluids.

Authors:  Frank Römer; Fernando Bresme; Jordan Muscatello; Dick Bedeaux; J Miguel Rubí
Journal:  Phys Rev Lett       Date:  2012-03-07       Impact factor: 9.161

2.  An enhanced version of the heat exchange algorithm with excellent energy conservation properties.

Authors:  P Wirnsberger; D Frenkel; C Dellago
Journal:  J Chem Phys       Date:  2015-09-28       Impact factor: 3.488

3.  Canonical dynamics: Equilibrium phase-space distributions.

Authors: 
Journal:  Phys Rev A Gen Phys       Date:  1985-03

4.  On the proper calculation of electrostatic interactions in solid-supported bilayer systems.

Authors:  In-Chul Yeh; Anders Wallqvist
Journal:  J Chem Phys       Date:  2011-02-07       Impact factor: 3.488

5.  Microscopic mechanism of thermomolecular orientation and polarization.

Authors:  Alpha A Lee
Journal:  Soft Matter       Date:  2016-10-26       Impact factor: 3.679

6.  Thermo-molecular orientation effects in fluids of dipolar dumbbells.

Authors:  Christopher D Daub; Per-Olof Åstrand; Fernando Bresme
Journal:  Phys Chem Chem Phys       Date:  2014-09-11       Impact factor: 3.676

7.  Hot Nanoparticles in Polar or Paramagnetic Liquids Interact as Monopoles.

Authors:  Daan Frenkel
Journal:  J Phys Chem B       Date:  2016-04-06       Impact factor: 2.991

8.  The rich phase behavior of the thermopolarization of water: from a reversal in the polarization, to enhancement near criticality conditions.

Authors:  Irene Iriarte-Carretero; Miguel A Gonzalez; Jeff Armstrong; Felix Fernandez-Alonso; Fernando Bresme
Journal:  Phys Chem Chem Phys       Date:  2016-07-20       Impact factor: 3.676

9.  Water polarization induced by thermal gradients: the extended simple point charge model (SPC/E).

Authors:  J A Armstrong; F Bresme
Journal:  J Chem Phys       Date:  2013-07-07       Impact factor: 3.488

10.  Water polarization under thermal gradients.

Authors:  Fernando Bresme; Anders Lervik; Dick Bedeaux; Signe Kjelstrup
Journal:  Phys Rev Lett       Date:  2008-07-09       Impact factor: 9.161

View more

北京卡尤迪生物科技股份有限公司 © 2022-2023.