Literature DB >> 28425508

Spin-state modulation of molecular FeIII complexes via inclusion in halogen-bonded supramolecular networks.

Ie-Rang Jeon1, Olivier Jeannin, Rodolphe Clérac, Mathieu Rouzières, Marc Fourmigué.   

Abstract

The cationic complex [Fe(qsal)2]+ (Hqsal = N-(8-quinolyl)salicylaldimine) is encapsulated in anionic halogen-bonded 1D and 2D networks derived from sym-triiodotrifluorobenzene, [(C6F3I3)Cl]- and [(C6F3I3)I]-. Structural analysis and magnetic measurements show that the spin-state of this complex can be modulated by its inclusion in supramolecular host frameworks.

Entities:  

Year:  2017        PMID: 28425508     DOI: 10.1039/c7cc01943b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Co-crystallisation as a modular approach to the discovery of spin-crossover materials.

Authors:  Lee T Birchall; Giada Truccolo; Lewis Jackson; Helena J Shepherd
Journal:  Chem Sci       Date:  2022-02-18       Impact factor: 9.825

2.  Connectivity and Topology Invariance in Self-Assembled and Halogen-Bonded Anionic (6,3)-Networks.

Authors:  Franck Meyer; Tullio Pilati; Konstantis F Konidaris; Pierangelo Metrangolo; Giuseppe Resnati
Journal:  Molecules       Date:  2017-11-24       Impact factor: 4.411

  2 in total

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