Literature DB >> 28414219

Anion Encapsulation Drives the Formation of Dimeric GdIII[15-metallacrown-5]3+ Complexes in Aqueous Solution.

Carmelo Sgarlata1, Alessandro Giuffrida1, Evan R Trivedi2, Vincent L Pecoraro2, Giuseppe Arena1.   

Abstract

Metallacrown complexes capable of sequestering dianions, as shown in the solid state, also exist in aqueous solution at neutral pH, as demonstrated by calorimetric and mass spectrometric data. The driving forces for the formation of these dimeric complexes in solution strongly depend on the chain length of the guest rather than its degree of unsaturation.

Entities:  

Year:  2017        PMID： 28414219      PMCID： PMC5496445          DOI： 10.1021/acs.inorgchem.6b03043

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  35 in total

1.  CATALYSIS. A speedy marriage in supramolecular catalysis.

Authors:  KaKing Yan; Makoto Fujita
Journal:  Science       Date:  2015-12-03       Impact factor: 47.728

2.  Stabilization of reactive organometallic intermediates inside a self-assembled nanoscale host.

Authors:  Dorothea Fiedler; Robert G Bergman; Kenneth N Raymond
Journal:  Angew Chem Int Ed Engl       Date:  2006-01-23       Impact factor: 15.336

3.  Structural and functional evolution of metallacrowns.

Authors:  Gellert Mezei; Curtis M Zaleski; Vincent L Pecoraro
Journal:  Chem Rev       Date:  2007-11       Impact factor: 60.622

4.  More chemistry in small spaces.

Authors:  Dariush Ajami; Julius Rebek
Journal:  Acc Chem Res       Date:  2012-05-10       Impact factor: 22.384

5.  A gemini guest triggers the self-assembly of a calixarene capsule in water at neutral pH.

Authors:  Carmela Bonaccorso; Carmelo Sgarlata; Giulia Grasso; Valeria Zito; Domenico Sciotto; Giuseppe Arena
Journal:  Chem Commun (Camb)       Date:  2011-04-11       Impact factor: 6.222

6.  Asymmetric spiroacetalization catalysed by confined Brønsted acids.

Authors:  Ilija Čorić; Benjamin List
Journal:  Nature       Date:  2012-03-14       Impact factor: 49.962

7.  Enhanced guest affinity and enantioselectivity through variation of the Gd3+ [15-metallacrown-5] side chain.

Authors:  Joseph T Grant; Joseph Jankolovits; Vincent L Pecoraro
Journal:  Inorg Chem       Date:  2012-05-02       Impact factor: 5.165

8.  Voltammetric characterization of redox-inactive guest binding to Ln(III)[15-Metallacrown-5] hosts based on competition with a redox probe.

Authors:  Joseph Jankolovits; Jeff W Kampf; Stephen Maldonado; Vincent L Pecoraro
Journal:  Chemistry       Date:  2010-06-18       Impact factor: 5.236

9.  HypCal, a general-purpose computer program for the determination of standard reaction enthalpy and binding constant values by means of calorimetry.

Authors:  Giuseppe Arena; Peter Gans; Carmelo Sgarlata
Journal:  Anal Bioanal Chem       Date:  2016-07-16       Impact factor: 4.142

10.  A Deep Cavitand Templates Lactam Formation in Water.

Authors:  Simone Mosca; Yang Yu; Jesse V Gavette; Kang-Da Zhang; Julius Rebek
Journal:  J Am Chem Soc       Date:  2015-11-11       Impact factor: 15.419
View more

北京卡尤迪生物科技股份有限公司 © 2022-2023.