Literature DB >> 28406640

Cobalt-Catalyzed Intramolecular Oxidative C(sp3)-H/N-H Carbonylation of Aliphatic Amides.

Li Zeng1, Shan Tang1, Dan Wang1, Yi Deng1, Jeng-Lung Chen2, Jyh-Fu Lee2, Aiwen Lei1,3.   

Abstract

A cobalt-catalyzed reaction protocol is developed to achieve the intramolecular oxidative C(sp3)-H/N-H carbonylation of aliphatic amides with CO. Various substituted propanamides are selectively transformed into corresponding succinimides in good to high yields. Notably, predominant selectivity for the carbonylation at the α-methyl groups of linear aliphatic amides is observed in this reaction system.

Entities:  

Year:  2017        PMID： 28406640     DOI： 10.1021/acs.orglett.7b00825

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  4 in total

Review 1.  Transition-Metal-Catalyzed, Coordination-Assisted Functionalization of Nonactivated C(sp3)-H Bonds.

Authors:  Bin Liu; Andrew M Romine; Camille Z Rubel; Keary M Engle; Bing-Feng Shi
Journal:  Chem Rev       Date:  2021-10-29       Impact factor: 60.622

2.  Anticancer Agents Derived from Cyclic Thiosulfonates: Structure-Reactivity and Structure-Activity Relationships.

Authors:  Amanda F Ghilardi; Elham Yaaghubi; Renan B Ferreira; Mary E Law; Yinuo Yang; Bradley J Davis; Christopher M Schilson; Ion Ghiviriga; Adrian E Roitberg; Brian K Law; Ronald K Castellano
Journal:  ChemMedChem       Date:  2022-05-23       Impact factor: 3.540

Review 3.  A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry.

Authors:  Carlo Sambiagio; David Schönbauer; Remi Blieck; Toan Dao-Huy; Gerit Pototschnig; Patricia Schaaf; Thomas Wiesinger; Muhammad Farooq Zia; Joanna Wencel-Delord; Tatiana Besset; Bert U W Maes; Michael Schnürch
Journal:  Chem Soc Rev       Date:  2018-08-28       Impact factor: 54.564

4.  Cobalt-catalyzed electrooxidative C-H/N-H [4+2] annulation with ethylene or ethyne.

Authors:  Shan Tang; Dan Wang; Yichang Liu; Li Zeng; Aiwen Lei
Journal:  Nat Commun       Date:  2018-02-23       Impact factor: 14.919
  4 in total

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