Literature DB >> 28406535

Burgess iridium(I)-catalyst for selective hydrogen isotope exchange.

Annina Burhop1, Raphail Prohaska1, Remo Weck1, Jens Atzrodt1, Volker Derdau1.   

Abstract

We have evaluated the commercially available Burgess catalyst in hydrogen isotope exchange reactions with several substrates bearing different directing group functionalities and have obtained moderate to high (50%-97%D) deuterium incorporations. The broad applicability in hydrogen isotope exchange reactions makes the Burgess catalyst a possible alternative compared to other commercially available iridium(I)-catalysts.
Copyright © 2017 John Wiley & Sons, Ltd.

Entities:  

Keywords:  Burgess catalyst; CH-activation; deuterium; hydrogen isotope exchange

Mesh：

Substances：

Year:  2017        PMID： 28406535     DOI： 10.1002/jlcr.3512

Source DB:  PubMed          Journal:  J Labelled Comp Radiopharm        ISSN： 0362-4803            Impact factor:   1.921


  3 in total

1.  NHC-Stabilized Iridium Nanoparticles as Catalysts in Hydrogen Isotope Exchange Reactions of Anilines.

Authors:  Mégane Valero; Donia Bouzouita; Alberto Palazzolo; Jens Atzrodt; Christophe Dugave; Simon Tricard; Sophie Feuillastre; Grégory Pieters; Bruno Chaudret; Volker Derdau
Journal:  Angew Chem Int Ed Engl       Date:  2020-01-29       Impact factor: 15.336

2.  Highly Selective Directed Iridium-Catalyzed Hydrogen Isotope Exchange Reactions of Aliphatic Amides.

Authors:  Mégane Valero; Remo Weck; Stefan Güssregen; Jens Atzrodt; Volker Derdau
Journal:  Angew Chem Int Ed Engl       Date:  2018-05-30       Impact factor: 15.336

3.  Comparison of Iridium(I) Catalysts in Temperature Mediated Hydrogen Isotope Exchange Reactions.

Authors:  Mégane Valero; Anurag Mishra; Jennifer Blass; Remo Weck; Volker Derdau
Journal:  ChemistryOpen       Date:  2019-08-01       Impact factor: 2.911
  3 in total

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