Literature DB >> 28405649

A ligand design with a modified naphthyridylamide for achieving the longest EMACs: the 1st single-molecule conductance of an undeca-nickel metal string.

Po-Jung Chen1, Marc Sigrist, Er-Chien Horng, Geng-Min Lin, Gene-Hsiang Lee, Chun-Hsien Chen, Shie-Ming Peng.   

Abstract

Striding to extend the length of metal-atom strings, oligo-α-pyridylamino ligands are modulated with naphthyridyl moieties leading to the undeca-nickel mixed-valence complexes [Ni11(bnatpya)4Cl2]4+ (1) and [Ni11(bnatpya)4Cl2]2+ (2). The first single-molecule conductance measurements of a linear undeca-nickel chain were performed.

Entities:  

Year:  2017        PMID： 28405649     DOI： 10.1039/c7cc01831b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Tetrairon(II) extended metal atom chains as single-molecule magnets.

Authors:  Alessio Nicolini; Marco Affronte; Daniel J SantaLucia; Marco Borsari; Benjamin Cahier; Matteo Caleffi; Antonio Ranieri; John F Berry; Andrea Cornia
Journal:  Dalton Trans       Date:  2021-06-08       Impact factor: 4.569

2.  Modulation of Band Gaps toward Varying Conductivities in Heterometallic One-Dimensional Chains by Ligand Alteration and Third Metal Insertion.

Authors:  Kazuhiro Uemura; Daiki Ito; Jenny Pirillo; Yuh Hijikata; Akinori Saeki
Journal:  ACS Omega       Date:  2020-11-13

3.  The Origin of Magnetic Anisotropy and Single-Molecule Magnet Behavior in Chromium(II)-Based Extended Metal Atom Chains.

Authors:  Andrea Cornia; Anne-Laure Barra; Vladimir Bulicanu; Rodolphe Clérac; Miguel Cortijo; Elizabeth A Hillard; Rita Galavotti; Alessandro Lunghi; Alessio Nicolini; Mathieu Rouzières; Lorenzo Sorace; Federico Totti
Journal:  Inorg Chem       Date:  2020-01-22       Impact factor: 5.165
  3 in total

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