| Literature DB >> 28402633 |
Abstract
Sixteen new angular dihydropyranocoumarins (1-16) and 24 known compounds were isolated from the roots of Peucedanum japonicum Thunb. The absolute configuration of diacylkhellactone was established by partial hydrolysis, the Mosher method, and X-ray crystallography. In addition, ECD spectroscopy was used to assign the absolute configurations of several of the angular dihydropyranocoumarins. Enantiomers were detected by RP-HPLC using MTPA esters while acyl migration of the substituents was observed in cis-monoacylkhellactones.Entities:
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Year: 2017 PMID： 28402633 DOI： 10.1021/acs.jnatprod.6b00947
Source DB: PubMed Journal: J Nat Prod ISSN： 0163-3864 Impact factor: 4.050