| Literature DB >> 28402015 |
Koki Ikemoto1, Ryo Kobayashi2, Sota Sato1, Hiroyuki Isobe1,2.
Abstract
A phenylene multiring with a corannulenoidal skeleton was synthesized. Geodesic constraints over 20 phenylene panels resulted in its nanometer-sized, bowl-shaped molecular structure, which was unequivocally revealed by crystallographic analysis. The crystal structure also showed the presence of a bowl-in-bowl dimeric assembly, which was driven by entropic factors in solution.Entities:
Keywords: macrocycles; meta-phenylene; molecular recognition; nanostructures; self-assembly
Year: 2017 PMID: 28402015 DOI: 10.1002/anie.201702063
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336