Literature DB >> 28401978

Cobalt-catalysed Markovnikov selective hydroboration of vinylarenes.

Jingying Peng1, Jamie H Docherty1, Andrew P Dominey2, Stephen P Thomas1.   

Abstract

A bipyridiyl-oxazoline cobalt catalyst tBuBPOCoCl2 has been developed for the Markovnikov selective hydroboration of alkenes using pinacolborane and NaOtBu as the in situ activator with up to >98 : 2 branched : linear selectivity (24 examples, 45-92% isolated yield).

Entities:  

Year:  2017        PMID： 28401978     DOI： 10.1039/c7cc01085k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Cationic Co(I)-Intermediates for Hydrofunctionalization Reactions: Regio- and Enantioselective Cobalt-Catalyzed 1,2-Hydroboration of 1,3-Dienes.

Authors:  Krishnaja Duvvuri; Kendra R Dewese; Mahesh M Parsutkar; Stanley M Jing; Milauni M Mehta; Judith C Gallucci; T V RajanBabu
Journal:  J Am Chem Soc       Date:  2019-04-25       Impact factor: 15.419

2.  Ligand-controlled cobalt-catalyzed regiodivergent hydroboration of aryl,alkyl-disubstituted internal allenes.

Authors:  Caizhi Wu; Shaozhong Ge
Journal:  Chem Sci       Date:  2020-02-05       Impact factor: 9.825

3.  Visible-Light Controlled Divergent Catalysis Using a Bench-Stable Cobalt(I) Hydride Complex.

Authors:  Enrico Bergamaschi; Frédéric Beltran; Christopher J Teskey
Journal:  Chemistry       Date:  2020-03-25       Impact factor: 5.236

4.  Regiodivergent hydrosilylation, hydrogenation, [2π + 2π]-cycloaddition and C-H borylation using counterion activated earth-abundant metal catalysis.

Authors:  Riaz Agahi; Amy J Challinor; Joanne Dunne; Jamie H Docherty; Neil B Carter; Stephen P Thomas
Journal:  Chem Sci       Date:  2019-04-08       Impact factor: 9.825

Review 5.  Emergence and Applications of Base Metals (Fe, Co, and Ni) in Hydroboration and Hydrosilylation.

Authors:  Sem Raj Tamang; Michael Findlater
Journal:  Molecules       Date:  2019-09-03       Impact factor: 4.411

6.  Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation.

Authors:  Meng-Yang Hu; Qiao He; Song-Jie Fan; Zi-Chen Wang; Luo-Yan Liu; Yi-Jiang Mu; Qian Peng; Shou-Fei Zhu
Journal:  Nat Commun       Date:  2018-01-15       Impact factor: 14.919
  6 in total

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