Facile Fabrication of BCN Nanosheet-Encapsulated Nano-Iron as Highly Stable Fischer-Tropsch Synthesis Catalyst.

The few layered boron carbon nitride nanosheets (BCNNSs) have attracted widespread attention in the field of heterogeneous catalysis. Herein, we report an innovative one-pot route to prepare the catalyst of BCNNSs-encapsulated sub-10 nm highly dispersed nanoiron particles. Then the novel catalyst was used in Fischer-Tropsch synthesis for the first time and it exhibited high activity and superior stability. At a high temperature of 320 °C, CO conversion could reach 88.9%, corresponding catalytic activity per gram of iron (iron time yield, FTY) of 0.9 × 10-4 molCO gFe-1 s-1, more than 200 times higher than that of pure iron. Notably, no obvious deactivation was observed after 1000 h running. The enhanced stability of the catalyst can be ascribed to the special encapsulated structure. Furthermore, the formation mechanism of highly dispersed iron nanoparticle also was elaborated. This approach opens the way to designing metal nanoparticles with both high stability and reactivity for nanocatalysts in hydrogenation application.