Literature DB >> 28393955

Benz-amidinato calcium iodide catalyzed aldehyde and ketone hydroboration with unprecedented functional group tolerance.

Sandeep Yadav1, Sanjukta Pahar, Sakya S Sen.   

Abstract

A benz-amidinato calcium compound, [PhC(NiPr)2CaI] (1), catalyzed hydroboration of a wide range of aldehydes and ketones using pinacolborane (HBpin) at room temperature is reported. The catalyst shows functional group tolerance even towards OH and NH groups. The strategy was further extended to imines.

Entities:  

Year:  2017        PMID： 28393955     DOI： 10.1039/c7cc02311a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Diplumbane-catalysed solvent- and additive-free hydroboration of ketones and aldehydes.

Authors:  Guoqi Zhang; Sihan Li; Haisu Zeng; Shengping Zheng; Michelle C Neary
Journal:  RSC Adv       Date:  2022-06-29       Impact factor: 4.036

Review 2.  s-Block Metal Catalysts for the Hydroboration of Unsaturated Bonds.

Authors:  Marc Magre; Marcin Szewczyk; Magnus Rueping
Journal:  Chem Rev       Date:  2022-03-07       Impact factor: 72.087

3.  Pincer-Supported Gallium Complexes for the Catalytic Hydroboration of Aldehydes, Ketones and Carbon Dioxide.

Authors:  Lingyu Liu; Siu-Kwan Lo; Cory Smith; Jose M Goicoechea
Journal:  Chemistry       Date:  2021-10-27       Impact factor: 5.020

4.  1-Alkali-metal-2-alkyl-1,2-dihydropyridines: Soluble Hydride Surrogates for Catalytic Dehydrogenative Coupling and Hydroboration Applications.

Authors:  Ross McLellan; Alan R Kennedy; Robert E Mulvey; Samantha A Orr; Stuart D Robertson
Journal:  Chemistry       Date:  2017-11-03       Impact factor: 5.236

5.  Enantiopure Calcium Iminophosphonamide Complexes: Synthesis, Photoluminescence, and Catalysis.

Authors:  Bhupendra Goswami; Thomas J Feuerstein; Ravi Yadav; Ralf Köppe; Sergei Lebedkin; Manfred M Kappes; Peter W Roesky
Journal:  Chemistry       Date:  2021-02-02       Impact factor: 5.236

6.  Donor-influenced Structure-Activity Correlations in Stoichiometric and Catalytic Reactions of Lithium Monoamido-Monohydrido-Dialkylaluminates.

Authors:  Lara E Lemmerz; Ross McLellan; Neil R Judge; Alan R Kennedy; Samantha A Orr; Marina Uzelac; Eva Hevia; Stuart D Robertson; Jun Okuda; Robert E Mulvey
Journal:  Chemistry       Date:  2018-06-13       Impact factor: 5.236
  6 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.