Literature DB >> 28393938

Reversible dinitrogen binding to [Cp'Fe(NHC)] associated with an N2-induced spin state change.

Matthias Reiners1, Dirk Baabe, Marc-Kevin Zaretzke, Matthias Freytag, Marc D Walter.   

Abstract

The 15-valence electron (VE), high-spin (S = 3/2) half-sandwich complex [Cp'Fe(IiPr2Me2)] (3; IiPr2Me2 = 1,3-di-iso-propyl-4,5-dimethylimidazol-2-yildene) reversibly coordinates N2 to form the 17VE, low-spin (S = 1/2) compound [Cp'Fe(IiPr2Me2)(η1-N2)] (4).

Entities:  

Year:  2017        PMID： 28393938     DOI： 10.1039/c7cc01535f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Nitrogenase-Relevant Reactivity of a Synthetic Iron-Sulfur-Carbon Site.

Authors:  Amy L Speelman; Ilija Čorić; Casey Van Stappen; Serena DeBeer; Brandon Q Mercado; Patrick L Holland
Journal:  J Am Chem Soc       Date:  2019-08-12       Impact factor: 15.419

2.  Synthesis and Reactivity of Iron Complexes with a Biomimetic SCS Pincer Ligand.

Authors:  Amy L Speelman; Kazimer L Skubi; Brandon Q Mercado; Patrick L Holland
Journal:  Inorg Chem       Date:  2021-01-14       Impact factor: 5.165
  2 in total

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