Literature DB >> 28390376

A Gaussian theory for fluctuations in simple liquids.

Matthias Krüger1, David S Dean2.   

Abstract

Assuming an effective quadratic Hamiltonian, we derive an approximate, linear stochastic equation of motion for the density-fluctuations in liquids, composed of overdamped Brownian particles. From this approach, time dependent two point correlation functions (such as the intermediate scattering function) are derived. We show that this correlation function is exact at short times, for any interaction and, in particular, for arbitrary external potentials so that it applies to confined systems. Furthermore, we discuss the relation of this approach to previous ones, such as dynamical density functional theory as well as the formally exact treatment. This approach, inspired by the well known Landau-Ginzburg Hamiltonians, and the corresponding "Model B" equation of motion, may be seen as its microscopic version, containing information about the details on the particle level.

Year:  2017        PMID: 28390376     DOI: 10.1063/1.4979659

Source DB:  PubMed          Journal:  J Chem Phys        ISSN: 0021-9606            Impact factor:   3.488


  3 in total

1.  Energy dissipation and fluctuations in a driven liquid.

Authors:  Clara Del Junco; Laura Tociu; Suriyanarayanan Vaikuntanathan
Journal:  Proc Natl Acad Sci U S A       Date:  2018-03-16       Impact factor: 11.205

2.  Transverse Density Fluctuations around the Ground State Distribution of Counterions near One Charged Plate: Stochastic Density Functional View.

Authors:  Hiroshi Frusawa
Journal:  Entropy (Basel)       Date:  2019-12-25       Impact factor: 2.524

3.  Stochastic Density Functional Theory on Lane Formation in Electric-Field-Driven Ionic Mixtures: Flow-Kernel-Based Formulation.

Authors:  Hiroshi Frusawa
Journal:  Entropy (Basel)       Date:  2022-04-01       Impact factor: 2.738

  3 in total

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