Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Nickel-(II)-Catalyzed N-Formylation and N-Acylation of Amines.

Literature DB >> 28375017

Nickel-(II)-Catalyzed N-Formylation and N-Acylation of Amines.

Rahul B Sonawane¹, Nishant K Rasal¹, Sangeeta V Jagtap¹.

Abstract

A highly efficient protocol of Ni(II) metal complex, [Ni(quin)2], catalyzing N-formylation and N-acylation of amines with moderate to excellent yields, using N,N-dimethylformamide and N,N-dimethylacetamide in the presence of imidazole, is described here. The protocol shows broad substrate scope for aliphatic, aromatic, and heterocyclic amines.

Entities: Chemical

Year: 2017 PMID： 28375017 DOI： 10.1021/acs.orglett.7b00660

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

Keyword Cloud
Cited

8 in total

1. Direct amidation of non-activated phenylacetic acid and benzylamine derivatives catalysed by NiCl₂.

Authors: Lidan Cheng; Xiaoping Ge; Longjiang Huang
Journal: R Soc Open Sci Date: 2018-02-21 Impact factor: 2.963

2. MoS₂-Catalyzed transamidation reaction.

Authors: Feng Zhang; Lesong Li; Juan Ma; Hang Gong
Journal: Sci Rep Date: 2019-02-22 Impact factor: 4.379

3. Magnetically recyclable silica-coated ferrite magnetite-K₁₀ montmorillonite nanocatalyst and its applications in O, N, and S-acylation reaction under solvent-free conditions.

Authors: Nitin Tandon; Shripad M Patil; Runjhun Tandon; Pushpendra Kumar
Journal: RSC Adv Date: 2021-06-16 Impact factor: 4.036

Nickel-(II)-Catalyzed N-Formylation and N-Acylation of Amines.

1. Direct amidation of non-activated phenylacetic acid and benzylamine derivatives catalysed by NiCl₂.

2. MoS₂-Catalyzed transamidation reaction.

3. Magnetically recyclable silica-coated ferrite magnetite-K₁₀ montmorillonite nanocatalyst and its applications in O, N, and S-acylation reaction under solvent-free conditions.

4. Efficient N-formylation of primary aromatic amines using novel solid acid magnetic nanocatalyst.

5. From amines to (form)amides: a simple and successful mechanochemical approach.

6. Promiscuous activity of C-acyltransferase from Pseudomonas protegens: synthesis of acetanilides in aqueous buffer.

Review 7. Recent Uses of N,N-Dimethylformamide and N,N-Dimethylacetamide as Reagents.

8. Imidazolium Chloride: An Efficient Catalyst for Transamidation of Primary Amines.