Sn- and Pd-Free Synthesis of D-π-A Organic Sensitizers for Dye-Sensitized Solar Cells by Cu-Catalyzed Direct Arylation.

<A variety of D-π-A-type functional organic dyes are facilely synthesized by direct C-H arylation catalyzed by inexpensive copper salts. Under optimized reaction conditions, a broad substrate scope with good functional group compatibility was demonstrated. Based on this synthetic strategy, three new dye sensitizers (CYL-5-7) were designed and fabricated for use in dye-sensitized solar cells (DSSCs). Photovoltaic characterization showed that these devices gave open-circuit voltages of 0.65-0.75 V, short-circuit currents of 5.90-12.60 mA cm-2 , and fill factors of 65.6-76.9 %, corresponding to power conversion efficiencies (PCEs) of 2.95-6.20 %. This work represents the first use of Cu-catalyzed C-H arylation for a step-saving, Sn-free synthesis of precursor dyes for DSSC applications.