Literature DB >> 28367579

Regioselective hydrosilylation of epoxides catalysed by nickel(ii) hydrido complexes.

Jan Wenz1, Hubert Wadepohl, Lutz H Gade.   

Abstract

Bench-stable nickel fluoride complexes bearing NNN pincer ligands have been employed as precursors for the regioselective hydrosilylation of epoxides at room temperature. A nickel hydride assisted epoxide opening is followed by the cleavage of the newly formed nickel oxygen bond by σ-bond metathesis with a silane.

Entities:  

Year:  2017        PMID： 28367579     DOI： 10.1039/c7cc01655g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Catalyzing the Hydrodefluorination of CF3-Substituted Alkenes by PhSiH3. H• Transfer from a Nickel Hydride.

Authors:  Chengbo Yao; Shuai Wang; Jack Norton; Matthew Hammond
Journal:  J Am Chem Soc       Date:  2020-01-24       Impact factor: 15.419

2.  Primary Alcohols via Nickel Pentacarboxycyclopentadienyl Diamide Catalyzed Hydrosilylation of Terminal Epoxides.

Authors:  Keri A Steiniger; Tristan H Lambert
Journal:  Org Lett       Date:  2021-10-06       Impact factor: 6.072

Review 3.  Synthesis and application in asymmetric catalysis of P-stereogenic pincer-metal complexes.

Authors:  Yijun Xiang; Qianyi Ge; Shulei Wu; Xing Zheng; Zehua Yang
Journal:  RSC Adv       Date:  2020-03-05       Impact factor: 4.036

4.  Markovnikov alcohols via epoxide hydroboration by molecular alkali metal catalysts.

Authors:  Guoqi Zhang; Haisu Zeng; Shengping Zheng; Michelle C Neary; Pavel A Dub
Journal:  iScience       Date:  2022-09-12
  4 in total

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