| Literature DB >> 28353341 |
Pavel M Usov1, Brittany Huffman1, Charity C Epley1, Matthew C Kessinger1, Jie Zhu1, William A Maza1, Amanda J Morris1.
Abstract
A highly robust metal-organic framework (MOF) constructed from Zr6 oxo clusters and Fe(III) porphyrin linkers, PCN-223-Fe was investigated as a heterogeneous catalyst for oxygen reduction reaction (ORR). Films of the framework were grown on a conductive FTO substrate and showed a high catalytic current upon application of cathodic potentials and achieved high H2O/H2O2 selectivity. In addition, the effect of the proton source on the catalytic performance was also investigated.Entities:
Keywords: Fe porphyrin; catalysis; electrochemistry; metal−organic framework; oxygen reduction reaction
Year: 2017 PMID: 28353341 DOI: 10.1021/acsami.7b01547
Source DB: PubMed Journal: ACS Appl Mater Interfaces ISSN: 1944-8244 Impact factor: 9.229