Literature DB >> 28337650

On the influence of a network on optically isotropic fluid phases with tetrahedral/octupolar order.

Helmut R Brand1,2, Harald Pleiner3.   

Abstract

We investigate the influence of transient or permanent elasticity on liquid phases with octupolar (tetrahedral) order, a question that has never been addressed before. The focus will be on optically isotropic liquid phases with tetrahedral order including the T d phase and the chiral T phase introduced by Fel. It turns out that the presence of both, a network as well as tetrahedral order can lead to the formation of chiral domains of both hands in an optically isotropic fluid due to a completely novel mechanism, thus providing a possible macroscopic explanation for recent experimental observations. We study in detail how elasticity influences the macroscopic dynamics of both, the T d and the T phase. The simultaneous presence of a transient network as well as of octupolar order is shown to lead to completely new cross-coupling phenomena for optically isotropic systems including transient dissipative elastic strains due to temperature gradients.

Keywords:  Soft Matter: Liquid crystals

Year:  2017        PMID: 28337650     DOI: 10.1140/epje/i2017-11523-7

Source DB:  PubMed          Journal:  Eur Phys J E Soft Matter        ISSN: 1292-8941            Impact factor:   1.890


  2 in total

1.  Cubic and tetragonal liquid crystal phases composed of non-chiral molecules: Chirality and macroscopic properties.

Authors:  Helmut R Brand; Harald Pleiner
Journal:  Eur Phys J E Soft Matter       Date:  2019-11-15       Impact factor: 1.890

2.  Spontaneous mirror symmetry breaking in benzil-based soft crystalline, cubic liquid crystalline and isotropic liquid phases.

Authors:  Tino Reppe; Silvio Poppe; Xiaoqian Cai; Yu Cao; Feng Liu; Carsten Tschierske
Journal:  Chem Sci       Date:  2020-04-30       Impact factor: 9.825

  2 in total

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